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- W2016351646 abstract "Abstract High-pressure mass spectrometric measurements were carried out to examine the mechanism of NO 3 − formation in pure gaseous ethyl nitrate and its binary mixtures with various bath gases. A novel reaction: NO 2 − + C 2 H 5 ONO 2 → NO 3 − + C 2 H 5 ONO occurring with an activation energy has been reported and evidence for collisional deactivation of the intermediate complex [NO 2 ·C 2 H 5 ONO 2 has been obtained. The calculations performed with semi-empirical MINDO/3 suggest that this reaction proceeds by the nucleopholic displacement mechanism. Attack of NO 2 − on H-atom of the methyl group prefers the formation of clustered ion NO 2 − sd C 2 H 5 ONO 2 , which is experimentally observed." @default.
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- W2016351646 date "1982-05-01" @default.
- W2016351646 modified "2023-09-25" @default.
- W2016351646 title "The mechanism of NO3− formation from gaseous ethyl nitrate" @default.
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- W2016351646 doi "https://doi.org/10.1016/0301-0104(82)85036-2" @default.
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