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- W2016358689 abstract "The formation of first-order paraelectric-ferroelectric phase boundaries in semiconducting crystals of the ferroelectrics K${mathrm{Ta}}_{0.65}$${mathrm{Nb}}_{0.35}$${mathrm{O}}_{3}$ and BaTi${mathrm{O}}_{3}$ has been studied. It is shown that in crystals having carrier concentrations greater than ${10}^{16}$ ${mathrm{cm}}^{ensuremath{-}3}$, sharp first-order phase boundaries can form during the paraelectric-ferroelectric phase transformation, and that such a transformation results in the formation of reproducible single-domain crystals. The direction of the cubic-to-tetragonal phase boundary is found to differ from a {110} lattice plane by approximately 5ifmmode^circelsetextdegreefi{}, i.e., the boundary-plane normal is 40ifmmode^circelsetextdegreefi{} from the direction of the crystal $c$ axis. This result is in excellent agreement with existing crystallographic theories. Data are also presented on the infrared photo-ionization absorption anisotropy and the electrical resistance anisotropy measured on a single-domain semiconducting crystal of K${mathrm{Ta}}_{0.65}$${mathrm{Nb}}_{0.35}$${mathrm{O}}_{3}$." @default.
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- W2016358689 title "Paraelectric-Ferroelectric Phase Boundaries in Semiconducting Perovskite-Type Crystals" @default.
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- W2016358689 doi "https://doi.org/10.1103/physrev.155.539" @default.
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