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- W2016359154 abstract "Chloro-oxobis(2,4-pentanedionato)vanadium(V)[VO(acac)2Cl] sensitizes the polymerization of methyl methacrylate when irradiated by wavelengths in the near ultra-violet. Under the experimental conditions employed ([VO(acac)2Cl] 0, the rate of photodecomposition exceeds the rate of initiation.A reaction mechanism is proposed based on an intramolecular photo-oxidation-reduction process which leads to the primary formation of a VIV chelate and a chlorine atom. In addition, monomer is considered to undergo an insertion reaction into the V—Cl bond of photo-excited VO(acac)2Cl, resulting in decomposition of the chelate by a non-radical route.Relevant kinetic parameters are evaluated." @default.
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- W2016359154 date "1974-01-01" @default.
- W2016359154 modified "2023-09-23" @default.
- W2016359154 title "Photoinitiation of polymerization by chloro-oxobis(2,4-pentanedionato)vanadium(V)" @default.
- W2016359154 doi "https://doi.org/10.1039/f19747002092" @default.
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