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- W2016360031 abstract "ABSTRACT The TRUEX process is being evaluated at the Idaho Chemical Processing Plant (ICPP) as a means to partition the actinides from acidic sodium-bearing waste (SBW). The mercury content of this waste averages 1 g/1. Because the chemistry of mercury has not been extensively evaluated in the TRUEX process, mercury was singled out as an element of interest. Radioactive mercury, 203Hg, was spiked into a simulated solution of SBW containing 1 g/1 mercury. Successive extraction batch contacts with the mercury spiked waste and successive scrubbing and stripping batch contacts of the mercury loaded TRUEX solvent (0.2 M CMPO-1.4 M TBP in dodecane) show that mercury will extract into and strip from the solvent. The extraction distribution coefficient for mercury, as HgCl2, from SBW having a nitric acid concentration of 1.4 M and a chloride concentration of 0.035 M was found to be 3. The stripping distribution coefficient was found to be 0.5 with 5 M HN03M and 0.077 with 0.25 M Na2C03. Because experiments described here show that mercury can be extracted from SBW and stripped from the solvent, a process has been developed to partition mercury from the actinides in SBW." @default.
- W2016360031 created "2016-06-24" @default.
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- W2016360031 date "1995-05-01" @default.
- W2016360031 modified "2023-10-18" @default.
- W2016360031 title "MERCURY EXTRACTION BY THE TRUEX PROCESS SOLVENT. II. SELECTIVE PARTITIONING OF MERCURY FROMCO-EXTRACTED ACTINIDES IN A SIMULATED ACIDIC ICPP WASTE STREAM1" @default.
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- W2016360031 doi "https://doi.org/10.1080/07366299508918285" @default.
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