Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016363336> ?p ?o ?g. }
Showing items 1 to 74 of
74
with 100 items per page.
- W2016363336 endingPage "269" @default.
- W2016363336 startingPage "257" @default.
- W2016363336 abstract "The 29Si chemical shifts of the series of disilanes Si2Ph6−xClx, Si2Ph6−xHx and Si2Cl6−xHx (for x = 0–6) were measured. The dependence of chemical shifts on change of substituents is discussed. It is not possible to predict 29Si chemical shifts exactly using published models. The influence may be discussed qualitatively, using the sum of electronegativity of substituents. For the series of chlorohydrogen disilanes the coupling constants 1J(SiSi), 1J(SiH) and 2J(SiH) are reported, for the series of phenylhydrogendisilanes most of the 1J(SiH) and 2J(SiH) are given. For the new compounds prepared physical data, IR and Raman spectra are reported. Die 29Si-chemischen Verschiebungen für die Disilanreihen Si2Ph6−xClx, Si2Ph6−xHx und Si2Cl6−xHx (x = 0–6) werden vermessen und in ihrer Substituentenabhängigkeit diskutiert. Es zeigt sich, dass keines der bisher veröffentlichten Konzepte zur Abhängigkeit der 29Si-chemischen Verschiebung eine genaue Voraussage der Lage der Resonanz zulässt. Qualitativ kann der Einfluss am ehesten über die Summe der Elektronegativität der Substituenten abgeschätzt werden. Für die Reihe der Chlorwasserstoffdisilane werden auch die Kopplungskonstanten 1J(SiSi), 1J(Si^z.sbnd;H) und2J(SiH), für die Reihe der Phenylwasserstoffdisilane ein Grossteil der 1J(SiH) und der 2J(SiH) bestimmt. Für die erstmalls rein dargestellten Substanzen werden die physikalischen Daten sowie IR- und Raman-Spektren angegeben." @default.
- W2016363336 created "2016-06-24" @default.
- W2016363336 creator A5006180050 @default.
- W2016363336 creator A5027577253 @default.
- W2016363336 date "1983-02-01" @default.
- W2016363336 modified "2023-10-03" @default.
- W2016363336 title "Vergleichende 29Si-NMR-untersuchungen an verschiedenen disilanderivaten" @default.
- W2016363336 cites W1990267794 @default.
- W2016363336 cites W1996585121 @default.
- W2016363336 cites W2003395345 @default.
- W2016363336 cites W2052402969 @default.
- W2016363336 cites W2054872263 @default.
- W2016363336 cites W2061360710 @default.
- W2016363336 cites W2074442889 @default.
- W2016363336 cites W2079573309 @default.
- W2016363336 cites W2315428138 @default.
- W2016363336 cites W2327642252 @default.
- W2016363336 cites W2329054089 @default.
- W2016363336 cites W2951430729 @default.
- W2016363336 doi "https://doi.org/10.1016/s0022-328x(00)98547-4" @default.
- W2016363336 hasPublicationYear "1983" @default.
- W2016363336 type Work @default.
- W2016363336 sameAs 2016363336 @default.
- W2016363336 citedByCount "56" @default.
- W2016363336 countsByYear W20163633362012 @default.
- W2016363336 countsByYear W20163633362013 @default.
- W2016363336 countsByYear W20163633362016 @default.
- W2016363336 countsByYear W20163633362018 @default.
- W2016363336 countsByYear W20163633362021 @default.
- W2016363336 countsByYear W20163633362023 @default.
- W2016363336 crossrefType "journal-article" @default.
- W2016363336 hasAuthorship W2016363336A5006180050 @default.
- W2016363336 hasAuthorship W2016363336A5027577253 @default.
- W2016363336 hasConcept C111429119 @default.
- W2016363336 hasConcept C120665830 @default.
- W2016363336 hasConcept C121332964 @default.
- W2016363336 hasConcept C147597530 @default.
- W2016363336 hasConcept C147789679 @default.
- W2016363336 hasConcept C177293861 @default.
- W2016363336 hasConcept C178790620 @default.
- W2016363336 hasConcept C185592680 @default.
- W2016363336 hasConcept C40003534 @default.
- W2016363336 hasConcept C71240020 @default.
- W2016363336 hasConceptScore W2016363336C111429119 @default.
- W2016363336 hasConceptScore W2016363336C120665830 @default.
- W2016363336 hasConceptScore W2016363336C121332964 @default.
- W2016363336 hasConceptScore W2016363336C147597530 @default.
- W2016363336 hasConceptScore W2016363336C147789679 @default.
- W2016363336 hasConceptScore W2016363336C177293861 @default.
- W2016363336 hasConceptScore W2016363336C178790620 @default.
- W2016363336 hasConceptScore W2016363336C185592680 @default.
- W2016363336 hasConceptScore W2016363336C40003534 @default.
- W2016363336 hasConceptScore W2016363336C71240020 @default.
- W2016363336 hasIssue "3" @default.
- W2016363336 hasLocation W20163633361 @default.
- W2016363336 hasOpenAccess W2016363336 @default.
- W2016363336 hasPrimaryLocation W20163633361 @default.
- W2016363336 hasRelatedWork W1972935442 @default.
- W2016363336 hasRelatedWork W2017906304 @default.
- W2016363336 hasRelatedWork W2059739996 @default.
- W2016363336 hasRelatedWork W2086895364 @default.
- W2016363336 hasRelatedWork W2298746276 @default.
- W2016363336 hasRelatedWork W2946254604 @default.
- W2016363336 hasRelatedWork W2950633153 @default.
- W2016363336 hasRelatedWork W4205143558 @default.
- W2016363336 hasRelatedWork W4205178407 @default.
- W2016363336 hasRelatedWork W2030721610 @default.
- W2016363336 hasVolume "243" @default.
- W2016363336 isParatext "false" @default.
- W2016363336 isRetracted "false" @default.
- W2016363336 magId "2016363336" @default.
- W2016363336 workType "article" @default.