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- W2016368002 abstract "The charge-remote fragmentation mechanism for n-alkyltriphenylphosphonium cations was examined through the use of high-energy collision-induced dissociation experiments on specifically deuterium-labeled isotopomers. In addition to the study of the charge-remote fragmentation mechanism other ions in the spectra, formed by so-called charge-proximate fragmentations, have also been studied. It was found that different processes are responsible for the formation of the ions in the spectra. A deuterium–hydrogen isotope effect of approximately 2 was measured for the 3,3-2H2 and 9,9-2H2 isotopomers, indicating that a C–H cleavage is a rate-determining step in the formation of corresponding charge-remote product ions as was reported for alkali-cationized fatty acid esters. Substantial insertion of hydrogens from the triphenylphosphine moiety into the fully labeled alkyl chain upon high-energy collision-induced dissociation points to the involvement of an excited state biradical in the processes which take place upon high-energy collision-induced dissociation." @default.
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- W2016368002 date "1999-06-01" @default.
- W2016368002 modified "2023-09-26" @default.
- W2016368002 title "Charge-remote and charge-proximate fragmentations in deuterium-labeled n-hexadecyltriphenylphosphonium cations upon high-energy collisional activation:" @default.
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- W2016368002 doi "https://doi.org/10.1016/s1387-3806(99)00020-2" @default.
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