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• W2016370407 abstract "The hydrogen bonded complexes between phenol derivatives and acetone (I), acetophenone (II) and benzophenone (III) have been studied in carbon tetrachloride solution by i.r. spectroscopy. The formation constants, the enthalpies of complex formation, the ΔνOH and ΔνCO values have been determined. For a given phenol derivative, the thermodynamic constants and ΔνOH are ordered according to I > II > III and the influence of a substituent implanted on the phenolic ring can be expressed by the Hammett relationship. The ϱ coefficients of the Hammett equation are related to the complexation enthalpies. The Badger—Bauer relation is valid for the three bases. The comparison with complexes involving other carbonyl bases allows to precise the influence of the substituent implanted on the carbonyl group. The ΔνOH values obey the dual substituent parameter equation using σI and σ+R; the ϱI/ϱR ratio is higher than one. The ΔνCO values are shown to depend on the complexation enthalpy and on the delocalization effect of the substituents." @default.
• W2016370407 created "2016-06-24" @default.
• W2016370407 creator A5054458934 @default.
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• W2016370407 date "1984-01-01" @default.
• W2016370407 modified "2023-10-03" @default.
• W2016370407 title "Infrared and Raman studies of hydrogen bonded complexes involving acetone, acetophenone and benzophenone—I. Thermodynamic constants and frequency shifts of the νOH and νCO stretching vibrations" @default.
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• W2016370407 doi "https://doi.org/10.1016/0584-8539(84)80054-9" @default.
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