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- W2016381004 abstract "A structurally realistic theoretical model for the pullulan chain is developed and refined to be consistent with the experimentally measured unperturbed dimensions of aqueous pullulan and with the temperature dependence of the unperturbed dimensions. The model is based on the mean structural geometry for an α-D-glucose residue recommended by Arnott and Scott and incorporates, in estimates of the conformational energy of the chain, a treatment of the gauche, or exo-anomeric, effect proposed by Abe and Mark. The refined chain model is used to generate computer drawn images of the pullulan chain in conformations typical of those characterizing the pullulan random coil in aqueous solution. The propensity of the pullulan chain trajectory to persist in its original direction is described in terms of an appropriately defined residue vector correlation function. The conformational energy functions associated with the refined chain model suggest, in contrast to some other recent treatments, that the trans-gauche rotational isomeric state of the C(5)—C(6) bond contributes to the configurational properties of oligo- and polysaccharides containing the α-D-glucopyranosyl-(1 → 6)-α-D-glucopyranosyl moiety." @default.
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- W2016381004 title "Theoretical interpretation of the unperturbed aqueous solution configuration of pullulan" @default.
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- W2016381004 doi "https://doi.org/10.1016/0141-8130(87)90030-4" @default.
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