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- W2016383350 abstract "Abstract A series of chiral tris‐(1,10)‐phenanthroline iron(II) complexes have been resolved by HPLC on chiral stationary phases based on either cellulose tris‐(3,5‐dimethylphenylcarbamate) or teicoplanin. At sub ambient temperatures, baseline separation of the enantiomers was observed for five different iron(II) complexes featuring substituted phenanthroline ligands. Dynamic HPLC profiles were observed near or above room temperature, indicating on‐column Δ/Λ enantiomerization. Rate constants for the Δ/Λ interconversion in free solution and during chromatography were obtained by thermal racemization experiments and by computer simulation of the HPLC dynamic plots, respectively. Chirality, 2009. © 2008 Wiley‐Liss, Inc." @default.
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- W2016383350 date "2008-07-24" @default.
- W2016383350 modified "2023-10-16" @default.
- W2016383350 title "Dynamic HPLC of stereolabile iron(II) complexes on chiral stationary phases" @default.
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- W2016383350 doi "https://doi.org/10.1002/chir.20612" @default.
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