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- W2016383491 abstract "A series of compounds of the type M3[Fe(CN)5CO]2·xH2O (M=Mn, Co, Ni, Cu, and Zn) have been studied by means of the X-ray diffraction powder patterns, magnetic measurements, infrared, electronic, and Mddotossbauer spectra. Three compounds M3[Fe(CN)5CO]2·xH2O (M=Mn, Co, and Ni) crystallize in the face-centered cubic system. Copper compound Cu3[Fe(CN)5CO]2·18.5H2O belongs to the tetragonal system, zinc compound Zn3[Fe(CN)5CO]2·13.5H2O being amorphous. The structure of these compounds is described as a three-dimensional framework of two octahedral coordination units FeC6 in the low spin state and MN10⁄3O8⁄3 in the high spin state. The back donation in the Fe(CN)5CO3− moiety is enhanced by the bridge formation through CN− and CO ligands, i.e. upon the formation of M3[Fe(CN)5CO]2·xH2O from the corresponding sodium salt." @default.
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- W2016383491 title "Characterization of Prussian Blue Analogs of the Type M<sub>3</sub>[Fe(CN)<sub>5</sub>CO]<sub>2</sub>·<i>x</i>H<sub>2</sub>O" @default.
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- W2016383491 doi "https://doi.org/10.1246/bcsj.55.733" @default.
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