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- W2016383733 abstract "Transitional layers at the metal/ceramic interface play an very important role in ceramic joining. In this study, sapphire blocks were ultrasonically dipped in liquid Sn-Zn-Al alloy. It is found that the ultrasound promoted rapid oxidation reaction of aluminum at the Sn-Zn-Al/sapphire interface at 230°C in the ambient atmosphere, resulting in the formation of a nano-crystalline α-Al2O3 layer (NCAL). In a ∼2nm boundary layer of the NCAL, the lattice matches the sapphire substrate well. Thus, a smooth transition of the lattice from sapphire to metal was formed through the NCAL. Ultrasonically soldered sapphire joints were made with Sn-Zn-Al as the filler alloy. Compressive shear strength of the joints reached 43-48MPa, which is relatively high comparing to other Al2O3 joints made of Sn alloys doped with Ti or Rear Earth elements. Thus, a new mechanism of ultrasonic soldering, i.e. building an oxide transitional layer on the surface of the solid, was revealed. We expect this sonochemical process to be applicable to other metal/oxide systems." @default.
- W2016383733 created "2016-06-24" @default.
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- W2016383733 date "2015-01-01" @default.
- W2016383733 modified "2023-09-25" @default.
- W2016383733 title "Building a nano-crystalline α-alumina layer at a liquid metal/sapphire interface by ultrasound" @default.
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- W2016383733 doi "https://doi.org/10.1016/j.ultsonch.2014.05.008" @default.
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