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- W2016391626 abstract "In a one-pot synthesis, highly branched synthetic glycopolymers have been prepared using the ‘Strathclyde Methodology’ involving a protected galactose monomethacrylate, a branching comonomer (ethylene glycol dimethacrylate or divinylbenzene) and a chain transfer agent (dodecanethiol) with 2,2′-azo-bis-isobutyronitrile as the source of radicals. Branching was confirmed via MALS/SEC and 1H NMR spectroscopy. One attractive feature of the methodology employed is that in a single-step procedure highly branched polymers with molar masses over a range of two orders of magnitude were obtained by fine-tuning the composition of comonomer and chain transfer agent mole feed ratio. Deprotection of the isopropylidene galactose functionalities on the polymers was achieved, leading to water-soluble and potentially bio-compatible synthetic glycopolymers with branched main chain architecture." @default.
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- W2016391626 date "2008-11-01" @default.
- W2016391626 modified "2023-10-16" @default.
- W2016391626 title "Synthesis and characterization of water-soluble densely branched glycopolymers" @default.
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- W2016391626 doi "https://doi.org/10.1016/j.reactfunctpolym.2008.08.004" @default.
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