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- W2016430002 abstract "Photoelectron spectroscopy was used to explore changes in Fermi level alignment, within the π−π* gap, arising from modifications to the coupling chemistry of conjugated phenylene ethynylene oligomers to the Au surface. Self-assembled monolayers were formed employing either thiol (4,4‘-ethynylphenyl-1-benzenethiol or OPE-T) or isocyanide (4,4‘-ethynylphenyl-1-benzeneisocyanide or OPE-NC) coupling. The electronic density of states in the valence region of the two systems are nearly identical with the exception of a shift to higher binding energy by about 0.5 eV for OPE-NC. Corresponding shifts appear in C(1s) spectra and in the threshold near EF. The lack of change in the optical absorption suggests that a rigid shift of the Fermi level within the π−π* gap is the major effect of modifying the coupling chemistry. Qualitative consideration of bonding in each case is used to suggest the influence of chemisorption-induced charge transfer as a potential explanation. Connections to other theoretical and experimental work on the effects of varying coupling chemistries are also discussed." @default.
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- W2016430002 date "2006-08-01" @default.
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- W2016430002 title "Fermi Level Alignment in Self-Assembled Molecular Layers: The Effect of Coupling Chemistry" @default.
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- W2016430002 doi "https://doi.org/10.1021/jp060228u" @default.
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