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- W2016436579 abstract "The mass spectra of 5,6,6a,7,12,12a-hexahydrobenzo[a]anthracene and 2-methoxy, 3-methoxy-, 4-methoxy and 1-methyl-4-methoxy derivatives are reported. Among the fragment ions observed under electron impact ionization, [C8H8]+· and [MC8H8]+· can be generated by a retro-Diels-Alder process. Studies of metastable ion reactions show these ions to be formed by fragmentation directly from the molecular ion. The CA spectra of the [C8H8]+· ions from the subject compounds were compared with spectra from ions of the same composition from various sources. From these data, kinetic energy release measurements and stereochemical considerations, it is concluded that these ions are formed by a stepwise, rather than a concerted mechanism." @default.
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- W2016436579 date "1984-04-01" @default.
- W2016436579 modified "2023-09-23" @default.
- W2016436579 title "A study of the electron impact induced retro-diels-alder process with selected 5,6,6a, 7,12,12a-hexahydrobenzo[a]anthracenes" @default.
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- W2016436579 doi "https://doi.org/10.1002/oms.1210190402" @default.
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