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- W2016444265 abstract "The photoelectron (PE) spectra of di-n-butylmethylphosphine, tri-n-butylphosphine, di-n-butylvinylphosphine, allyldi-n-butylphosphine, di-n-butylphenylphosphine, and benzyldi-n-butylphosphine, have been interpreted to exclude n/π-, d/π- and inductive interactions between the α- and β-phosphinyl substituents and the π-electron systems. Instead, PC/π (hyperconjugative)-interaction has been detected in all these π-systems for the first time; the vinyl-, phenyl-, allyl- and benzylphosphines must exist in ground-state conformations which allow hyperconjugation. A comparison with corresponding vinyl- and allysilanes suggests that, contrary to the vinyl-phosphines, d/π-conjugation is important in vinylsilanes. The CNDO/2-method is used to specify phosphine conformations more fully and to support the new conformational conclusions theoretically." @default.
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- W2016444265 date "1975-01-01" @default.
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- W2016444265 title "Molecular conformation and hyperconjugation. P-C-hyperconjugation and the conformation of vinyl-, allyl-, phenyl- and benzylphosphines" @default.
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