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- W2016455092 abstract "Mass spectra, ionization efficiency curves for parent and fragment ions and breakdown curves for these ions were determined for 1,5-hexadiyne, at different times following ionization by the method of trapped ion mass spectroscopy (TIMS). At short delay times (in the microsecond range) the parent ion C6II6+6 at m/z = 78, is the ion of lowest appearance potential. At longer delay times (in the millisecond range) the fragment ion C6H5+, at m/z = 77, is the ion of lowest appearance potential. These results are explained by the isomerization of the 1,5-hexadiyne ion to the more stable benzene ion structure, followed by dissociation to a phenyl ion and a hydrogen atom pair." @default.
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- W2016455092 title "Time-dependent mass spectra and breakdown graphs.I. 1,5-hexadiyne" @default.
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- W2016455092 doi "https://doi.org/10.1016/0020-7381(80)85029-7" @default.
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