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- W2016455911 abstract "The regioselectivity of the hydroboration of the methylchlorovinylsilanes, ClnMe3−nSiCHCH2 (n= 0 − 3), has been investigated using BH3←THF, 9-BBN, disiamyl- and dicyclohexylborane. Methylation of the adducts with methylmagnesium bromide is complicated by formation of tetraalkylboronates. Alkaline hydrogen peroxide oxidation of the boronates gives reasonable yields of the corresponding α- and β-trimethylsilylethanols forn= 0 and 1. Forn= 2 and 3, conversion of the adducts to the corresponding α- and β- deuteroethylsilanes by treatment with excess sodium methoxide in methanol-0-d provides a more effective means of derivatization. Addition of the alkenes,n= 2 or 3, to excess BH3←THF givesca. 90% of the α-boro-organo-chlorosilanes. For all of the alkenes, the dialkylboranes giveca. 80% of the β-boron adducts." @default.
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- W2016455911 date "1977-08-01" @default.
- W2016455911 modified "2023-10-03" @default.
- W2016455911 title "Regioselective hydroborations of methylvinylchlorosilanes" @default.
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- W2016455911 doi "https://doi.org/10.1016/s0022-328x(00)80866-9" @default.
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