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- W2016456859 abstract "A criterion A is introduced for the classification of stationary phase polarity. It is evaluated from the ratio of retention time differences for adjacent n-alkanes: A = (t′Rn+1 - t′Rn)/(t′Rn - t′Rn−). The polarity criterion A represents dispersive interactions of the methylene group with the stationary phase. Its depends on the structure and the number of functional groups in the stationary phase and its temperatue: A = a exp (bT−1). The constants a and b have an unequivocal physical meaning, and allow the prediction of the polarity of a stationary phase at any temperature. The influence of pressure and carrier gas flow-rate on the polarity criterion A were found to be insignificant. The high precision of the evaluation of criterion A leads to a high discrimination of stationary phase polarities. It allows the in situ control of the actual polarity of the stationary phase used and is thus a controlling parameter of the reliability of a separation system. Consequences for selection of stationary phases are discussed." @default.
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- W2016456859 date "1981-11-01" @default.
- W2016456859 modified "2023-09-29" @default.
- W2016456859 title "New criterion for polarity of stationary phases in gas chromatography" @default.
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- W2016456859 doi "https://doi.org/10.1016/s0021-9673(00)88068-1" @default.
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