FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016457559> ?p ?o ?g. }

• W2016457559 endingPage "7153" @default.
• W2016457559 startingPage "7147" @default.
• W2016457559 abstract "Owing to its high surface area and intrinsic reactivity, ferrihydrite serves as a dominant sink for numerous metals and nutrients in surface environments and is a potentially important terminal electron acceptor for microbial respiration. Introduction of Fe (II), by reductive dissolution of Fe(III) minerals, for example, converts ferrihydrite to Fe phases varying in their retention and reducing capacity. While Fe(II) concentration is the master variable dictating secondary mineralization pathways of ferrihydrite, here we reveal thatthe kinetics of conversion and ultimate mineral assemblage are a function of competing mineralization pathways influenced by pH and stabilizing ligands. Reaction of Fe(II) with ferrihydrite results in the precipitation of goethite, lepidocrocite, and magnetite. The three phases vary in their precipitation extent, rate, and residence time, all of which are primarily a function of Fe(II) concentration and ligand type (Cl, SO4, CO3). While lepidocrocite and goethite precipitate over a large Fe(II) concentration range, magnetite accumulation is only observed at surface loadings greater than 1.0 mmol Fe(II)/g ferrihydrite (in the absence of bicarbonate). Precipitation of magnetite induces the dissolution of lepidocrocite (presence of Cl) or goethite (presence of SO4), allowing for Fe(III)-dependent crystal growth. The rate of magnetite precipitation is a function of the relative proportions of goethite to lepidocrocite; the lower solubility of the former Fe (hydr)oxide slows magnetite precipitation. A one unit pH deviation from 7, however, either impedes (pH 6) or enhances (pH 8) magnetite precipitation. In the absence of magnetite nucleation, lepidocrocite and goethite continue to precipitate at the expense of ferrihydrite with near complete conversion within hours, the relative proportions of the two hydroxides dependent upon the ligand present. Goethite also continues to precipitate at the expense of lepidocrocite in the absence of chloride. In fact, the rate and extent of both goethite and magnetite precipitation are influenced by conditions conducive to the production and stability of lepidocrocite. Thus, predicting the secondary mineralization of ferrihydrite, a process having sweeping influences on contaminant/nutrient dynamics, will need to take into consideration kinetic restraints and transient precursor phases (e.g., lepidocrocite) that influence ensuing reaction pathways." @default.
• W2016457559 created "2016-06-24" @default.
• W2016457559 creator A5044660683 @default.
• W2016457559 creator A5052090764 @default.
• W2016457559 creator A5083714165 @default.
• W2016457559 date "2005-08-18" @default.
• W2016457559 modified "2023-10-14" @default.
• W2016457559 title "Competing Fe(II)-Induced Mineralization Pathways of Ferrihydrite" @default.
• W2016457559 cites W1503861105 @default.
• W2016457559 cites W1553800996 @default.
• W2016457559 cites W1970433028 @default.
• W2016457559 cites W1975849245 @default.
• W2016457559 cites W2006223922 @default.
• W2016457559 cites W2006367555 @default.
• W2016457559 cites W2034260620 @default.
• W2016457559 cites W2040901305 @default.
• W2016457559 cites W2048268824 @default.
• W2016457559 cites W2060718840 @default.
• W2016457559 cites W2067856736 @default.
• W2016457559 cites W2068436354 @default.
• W2016457559 cites W2081326796 @default.
• W2016457559 cites W2091913250 @default.
• W2016457559 cites W2115528621 @default.
• W2016457559 cites W2126129862 @default.
• W2016457559 cites W2127197558 @default.
• W2016457559 cites W2133825649 @default.
• W2016457559 cites W2165888175 @default.
• W2016457559 cites W4252878955 @default.
• W2016457559 cites W4255412919 @default.
• W2016457559 doi "https://doi.org/10.1021/es050666z" @default.
• W2016457559 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16201641" @default.
• W2016457559 hasPublicationYear "2005" @default.
• W2016457559 type Work @default.
• W2016457559 sameAs 2016457559 @default.
• W2016457559 citedByCount "475" @default.
• W2016457559 countsByYear W20164575592012 @default.
• W2016457559 countsByYear W20164575592013 @default.
• W2016457559 countsByYear W20164575592014 @default.
• W2016457559 countsByYear W20164575592015 @default.
• W2016457559 countsByYear W20164575592016 @default.
• W2016457559 countsByYear W20164575592017 @default.
• W2016457559 countsByYear W20164575592018 @default.
• W2016457559 countsByYear W20164575592019 @default.
• W2016457559 countsByYear W20164575592020 @default.
• W2016457559 countsByYear W20164575592021 @default.
• W2016457559 countsByYear W20164575592022 @default.
• W2016457559 countsByYear W20164575592023 @default.
• W2016457559 crossrefType "journal-article" @default.
• W2016457559 hasAuthorship W2016457559A5044660683 @default.
• W2016457559 hasAuthorship W2016457559A5052090764 @default.
• W2016457559 hasAuthorship W2016457559A5083714165 @default.
• W2016457559 hasConcept C107054158 @default.
• W2016457559 hasConcept C111696902 @default.
• W2016457559 hasConcept C121332964 @default.
• W2016457559 hasConcept C147789679 @default.
• W2016457559 hasConcept C150394285 @default.
• W2016457559 hasConcept C153294291 @default.
• W2016457559 hasConcept C178790620 @default.
• W2016457559 hasConcept C179104552 @default.
• W2016457559 hasConcept C185592680 @default.
• W2016457559 hasConcept C191897082 @default.
• W2016457559 hasConcept C192562407 @default.
• W2016457559 hasConcept C2777697756 @default.
• W2016457559 hasConcept C2777781897 @default.
• W2016457559 hasConcept C2777787761 @default.
• W2016457559 hasConcept C2780191927 @default.
• W2016457559 hasConcept C2780804967 @default.
• W2016457559 hasConcept C537208039 @default.
• W2016457559 hasConcept C88380143 @default.
• W2016457559 hasConceptScore W2016457559C107054158 @default.
• W2016457559 hasConceptScore W2016457559C111696902 @default.
• W2016457559 hasConceptScore W2016457559C121332964 @default.
• W2016457559 hasConceptScore W2016457559C147789679 @default.
• W2016457559 hasConceptScore W2016457559C150394285 @default.
• W2016457559 hasConceptScore W2016457559C153294291 @default.
• W2016457559 hasConceptScore W2016457559C178790620 @default.
• W2016457559 hasConceptScore W2016457559C179104552 @default.
• W2016457559 hasConceptScore W2016457559C185592680 @default.
• W2016457559 hasConceptScore W2016457559C191897082 @default.
• W2016457559 hasConceptScore W2016457559C192562407 @default.
• W2016457559 hasConceptScore W2016457559C2777697756 @default.
• W2016457559 hasConceptScore W2016457559C2777781897 @default.
• W2016457559 hasConceptScore W2016457559C2777787761 @default.
• W2016457559 hasConceptScore W2016457559C2780191927 @default.
• W2016457559 hasConceptScore W2016457559C2780804967 @default.
• W2016457559 hasConceptScore W2016457559C537208039 @default.
• W2016457559 hasConceptScore W2016457559C88380143 @default.
• W2016457559 hasIssue "18" @default.
• W2016457559 hasLocation W20164575591 @default.
• W2016457559 hasLocation W20164575592 @default.
• W2016457559 hasOpenAccess W2016457559 @default.
• W2016457559 hasPrimaryLocation W20164575591 @default.
• W2016457559 hasRelatedWork W1170235028 @default.
• W2016457559 hasRelatedWork W1974796734 @default.
• W2016457559 hasRelatedWork W1992681878 @default.
• W2016457559 hasRelatedWork W2034384450 @default.
• W2016457559 hasRelatedWork W2050975751 @default.
• W2016457559 hasRelatedWork W2070912856 @default.

• next