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- W2016459306 abstract "We demonstrate that Cu(111) surfaces pre-covered with a submonolayer of copper oxide or metallic nickel are suitable model-templates for the selective adsorption and/or localized functionalization of functional molecules such as different free base porphyrins and metalloporphyrins. The oxide/Cu(111) model-template is able to steer the adsorption of tetraphenylporphyrins (TPP): 2HTPP selectively adsorbs on the bare Cu areas, and for CoTPP anchoring at the rim of the copper oxide islands is found. On the Ni/Cu(111) model-template TPP molecules are pinned on the Ni areas while they are mobile on the bare Cu surface. Interestingly, adsorption of free base octaethylporphyrin on Ni/Cu(111) leads to a local functionalization, namely the metalation to NiOEP on the Ni areas. Model-template preparation and characterization by scanning tunneling microscopy is performed at room temperature." @default.
- W2016459306 created "2016-06-24" @default.
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- W2016459306 date "2013-02-28" @default.
- W2016459306 modified "2023-09-26" @default.
- W2016459306 title "Towards the engineering of molecular nanostructures: local anchoring and functionalization of porphyrins on model-templates" @default.
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- W2016459306 doi "https://doi.org/10.1088/0957-4484/24/11/115305" @default.
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