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- W2016476505 abstract "Abstract Nuclear (1H, 13C) magnetic resonance methods have been widely applied to the study of electronic structure of the hydrogen bond, proton transfer phenomena and dynamics of hydrogen bond formation in the phenoltriethylamine complexes in the temperature range of 100–300 K. Phenotic acids with triethylamine form a 1:1 complex whose nature in solution may be a simple hydrogen-bonded molecular complex or a hydrogen-bonded ion-pair depending on the acidic property of phenol. Thermodynamic and kinetics quantities of this molecular complex/ion pair tautomerism have been evaluated and results obtained will be discussed in relations to the potential energy profile of the hydrogen bonds. In addition the chemical shift of proton directly engaged in the hydrogen bond and the chemical shift of the oxygen bearing carbon of the phenol ring in a molecular complex (H⋯N) and in ion-pair (O−H⋯N+) have been estimated. Those NMR parameters will be discussed in relation to the electronic structure of the hydrogen bond." @default.
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- W2016476505 date "1980-01-01" @default.
- W2016476505 modified "2023-09-27" @default.
- W2016476505 title "Nuclear (1H, 13C) magnetic resonance studies of the proton transfer processes in hydrogen bonded complexes in aprotic solvents" @default.
- W2016476505 doi "https://doi.org/10.1016/s0020-1693(00)92040-1" @default.
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