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- W2016479072 abstract "Abstract 13 C and 31 P NMR data are reported for a series of phosphonate carbanions. In comparison with related uncharged molecules, the values of 1 J (PC) are rather large. This is discussed with the help of some INDO‐SCPT spin‐spin coupling calculations, which reveal that while the positive contact term makes the dominant contribution to these couplings, the negative orbital term also plays an important role. The signs of 1 J (PC) and 1 J (CH) are predicted to be positive in all cases. Support for the proposal of a planar anionic carbon atom is forthcoming from the INDO‐SCPT calculations." @default.
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- W2016479072 date "1985-01-01" @default.
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- W2016479072 title "NMR studies of phosphonate carbanions: Influence of substituents on1J(PC) and1J(CH) and some INDO calculations" @default.
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- W2016479072 doi "https://doi.org/10.1002/mrc.1260230113" @default.
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