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- W2016481451 abstract "In this Letter, we describe a novel approach for the general and enantioselective synthesis of a diverse array of small to large 1-azabicyclo[m.n.0]alkyl ring systems with an embedded olefin handle for further functionalization. The stereochemistry is established via a highly diastereoselective indium-mediated allylation of an Ellman sulfinimine in greater than 9:1 dr, which is readily separable by column chromatography to afford a single diastereomer. This methodology allows for the rapid preparation of 1-azabicyclo[m.n.0]alkane ring systems that are not readily accessible through any other chemistry in excellent overall yields and, for many systems, the only enantioselective preparation reported to date." @default.
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- W2016481451 date "2013-03-01" @default.
- W2016481451 modified "2023-10-17" @default.
- W2016481451 title "A general, enantioselective synthesis of 1-azabicyclo[m.n.0]alkane ring systems" @default.
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- W2016481451 doi "https://doi.org/10.1016/j.tetlet.2013.01.041" @default.
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