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- W2016503587 abstract "The instability of Eu complexes against ultraviolet (UV) light irradiation is an important problem to solve before they can be practically applied in white light-emitting diodes. A novel technique of encapsulating tris(2-thenoyltrifluoroacetonato)(1,10-phenanthroline)europium(III) [Eu(TTA) 3 phen] was investigated using high-pressure annealing (solvothermal process) as a final process in the sol–gel synthesis. The photoluminescence and excitation spectra of encapsulated Eu(TTA) 3 phen samples synthesized by solvothermal and conventional annealing processes were almost the same. A half brightness time of 589 min was achieved while irradiating with UV light of 360 nm and 5 mW/cm 2 by optimization of ammonia concentration and annealing temperature. The longest half brightness time was longer than that of encapsulated Eu(TTA) 3 phen synthesized by conventional thermal treatment. One possible reason for this result is that the chemical reaction of the sol–gel based glass network occurs more efficiently with high-pressure annealing. As a result, a high encapsulating efficiency was achieved owing to the small amount of organic component in the sol–gel derived glass network." @default.
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- W2016503587 date "2011-01-01" @default.
- W2016503587 modified "2023-10-16" @default.
- W2016503587 title "Improved Optical Degradation Characteristics of Eu Complex Encapsulated by High-Pressure Annealing" @default.
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- W2016503587 doi "https://doi.org/10.1143/jjap.50.01bf02" @default.
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