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- W2016520908 abstract "Tetraphenylcyclopentadienone is rapidly reduced by methyl phosphinate in the presence of base, the major products being 2,3,4,5-tetraphenylcyclopent-3-enone (3) and dimethyl phosphonate, formed together with small amounts of trans- and cis-2,3,4,5-tetraphenylcyclopent-2-enone and 4- and 5-hydroxy-2,3,4,5-tetraphenylcyclopent-2-enones, (5) and (6). A mechanism involving decomposition of the monoanion of methyl phosphinate to hydride ion and methyl phosphenite is suggested to account for the products formed. No compounds with carbon–phosphorus bonds were detected." @default.
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- W2016520908 date "1975-01-01" @default.
- W2016520908 modified "2023-10-18" @default.
- W2016520908 title "Organophosphorus intermediates. Part VI. Base-catalysed reaction of methyl phosphinate with tetraphenylcyclopentadienone" @default.
- W2016520908 doi "https://doi.org/10.1039/p19750001876" @default.
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