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- W2016547758 abstract "The X-band EPR spectra of [(H2O)5CrIII–CHCl2]2+, [(H2O)5CrIII–CHCBr2]2+, [(H2O)5CrIII–CH3]2+, [(H2O)5CrIII–CH2CO2H]2+ and [(H2O)5CrIII–CH(CH3)OC2H5]2+ were measured at liquid helium temperatures. For all complexes the major derivative signal is observed at g′perp ≈ 4 with weaker signals at g′par ≈ 2 and g′ ≈ 5.9. The signals broaden with increasing temperature and can not be observed at T ≥ 20 K. the low-temperature spectra could readily be simulated by using the spin Hamiltonian formalism for S = 3/2 with axial and rhombic zero-field splitting parameters D = −1.6 cm−1 and E/D = 0.06, respectively. Based on these results the (H2O)5Cr–R2+ complexes studied here are best described as chromium(III) compounds with a covalent chromium–carbon bond. In accord with expectations, this bond has a considerably larger covalent nature than the Cr–X bond, where X = halide, etc." @default.
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- W2016547758 date "2000-01-01" @default.
- W2016547758 modified "2023-09-26" @default.
- W2016547758 title "EPR Measurements corroborate information concerning the nature of (H2O)5CrIII–alkyl complexes" @default.
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- W2016547758 doi "https://doi.org/10.1039/b004755o" @default.
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