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- W2016554227 abstract "Abstract The ion exchange between divalent cations in anionic micellar systems were investigated by a fluorescence quenching technique using the anionic ruthenium complex RuL 4− 3 (L=4, 4′-dicarboxy-2, 2′-bipyridine) as an extramicellar probe and the N, N′-dimethyl-4, 4′-bipyridinium ion (MV 2+ ) as the quencher. Competitive ion exchange at the micellar surface between the divalent quencher counterion (MV 2+ ) and the divalent hexamethylethylenediammonium (HED 2+ ) counterion can be adequately described with a simple pseudophase ion-exchange formalism. The counterion exchange selectivity coefficients are K MV/HED =1.3 and 1.4 for HED-decyl sulfate [HED(DeS) 2 ] and HED-dodecylsulfate [HED(DS) 2 ] micelles, respectively. These results show that the MV 2+ cation only slightly more strongly bound to the micelle aggregates than the HED 2+ cation." @default.
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- W2016554227 date "1999-10-01" @default.
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- W2016554227 title "Ion exchange between divalent counterions in anionic micellar solution" @default.
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- W2016554227 doi "https://doi.org/10.1016/s0022-2313(99)00050-2" @default.
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