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- W2016559424 abstract "Ion-exchange reactions of Na2Cu2TeO6 with excess of lithium nitrate at low temperature (300 °C) readily resulted in an isostructural honeycomb ordered monoclinic layered structure Li2Cu2TeO6, otherwise inaccessible by direct solid state high temperature reactions. Similarly, Li2Ni2TeO6(I) stabilized approximately in equal amounts in both of the known P2-type polymorphs (P6(3)/mcm and P6(3)22) was synthesized as an ion-exchange reaction product from Na2Ni2TeO6 using a melt of lithium nitrate. Additionally, a unique tellurium containing oxide Li2Ni2TeO6(II) without the honeycomb ordering of Ni(2+)/Te(6+) ions has been obtained for the first time by the direct high temperature (800-900 °C) synthesis. The oxides were investigated by refinement of powder X-ray diffraction patterns, room temperature magnetization experiments along with Raman spectroscopy and photoluminescence measurements. A structural model has been suggested for the metastable Li2Ni2TeO6(II) and the presence of structural disorder was evidenced in the broadening of the Raman bands and the intense broad photoluminescence (PL) spectra obtained for Li2Ni2TeO6(II)." @default.
- W2016559424 created "2016-06-24" @default.
- W2016559424 creator A5041546735 @default.
- W2016559424 creator A5051962928 @default.
- W2016559424 creator A5054480158 @default.
- W2016559424 date "2013-01-01" @default.
- W2016559424 modified "2023-10-17" @default.
- W2016559424 title "Formation of honeycomb ordered monoclinic Li2M2TeO6 (M = Cu, Ni) and disordered orthorhombic Li2Ni2TeO6 oxides" @default.
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- W2016559424 doi "https://doi.org/10.1039/c3dt51604k" @default.
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