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- W2016579061 abstract "The force required to stretch a polymer chain by 1% (f value) was calculated from experimental values of elastic moduli E1 in the direction of molecular axis and the cross-sectional area of the molecule of 25 well known polymers. The f value is mainly dependent on the conformation of a molecule and almost independent of side groups. The f values of polymers of various types of conformation may be summarized as follows: T type, 4−5 × 10−5 dyne; TGTG type, 1.5 × 10−5 dyne; TG(3/1) type, 1 × 10−5 dyne; T′G′ (7/2) type, 0.58 × 10−5 dyne; T′G′ (4/1) type, 0.36 × 10−5 dyne; TTGG type, 0.29 × 10−5 dyne; where T, G, and G mean trans, gauche and minus gauche, respectively, and the numbers in the parentheses denote helical structures. The reason for an anomalous apparent E1 value of nylon 6 (α-form) previously reported was elucidated; it was confirmed that E1 exhibits a value expected for a polymer with a nearly extended zigzag conformation." @default.
- W2016579061 created "2016-06-24" @default.
- W2016579061 creator A5043481770 @default.
- W2016579061 creator A5065849990 @default.
- W2016579061 date "2007-03-07" @default.
- W2016579061 modified "2023-10-14" @default.
- W2016579061 title "relation between the polymer conformation and the elastic modulus of the crystalline region of polymer" @default.
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- W2016579061 doi "https://doi.org/10.1002/polc.5070310108" @default.
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