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- W2016586227 abstract "150 years of German–Japanese friendship was celebrated last year. This issue of Chemistry – An Asian Journal is a special issue dedicated to the occasion. It features top contributions from around the world, including an Essay on the development of biocatalytic processes in both countries, Focus Reviews on molecular spintronics and nonlinear optical properties of confined dyes, as well as over 30 original research papers. The cover picture by Kazuyuki Tatsumi et al. highlights the connection between Germany and Japan, just as the two iron centers in an anthracene double sandwich complex are electronically coupled, as reported by this group as a Full paper on page 1231 ff. No Abstract Molecular Spintronics In their Focus review on page 1154 ff., Masahiro Yamashita et al. summarize the results of studies on the switching of the Kondo signal for double-decker bis(phthalocyaninato)terbium(III) lanthanoid single-molecule magnets, [TbPc2], on Au(111), which is a spin one-half (S=1/2) Kondo system because of the ligand spin, not the Tb3+ spin. In these sandwich complexes, the upper ligand can be rotated in a controlled manner, thereby switching the ligand spin on and off. Thus, information can be encoded at the single-molecule level by controlling the molecular spin through an electric current. Metal Hydrides An experimental/computational study on the thermal activation of ammonia by cationic transition-metal hydrides MH+ is presented by Robert Kretschmer, Maria Schlangen, and Helmut Schwarz in their Full paper on page 1214 ff. Amide formation accompanied by loss of H2 is observed for all ions except ZnH+. Further, proton transfer takes place for the middle and late transition metals from MnH+ to ZnH+. Finally, ligand exchange under the formation of M(NH3)+ proceeds only when using CrH+, CoH+, and NiH+. The underlying mechanisms have been uncovered by labeling experiments and quantum chemical calculations, respectively." @default.
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- W2016586227 date "2012-05-25" @default.
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- W2016586227 title "Cover Picture: Naphthalene and Anthracene Complexes Sandwiched by Two {(Cp*)FeI} Fragments: Strong Electronic Coupling between the FeICenters (Chem. Asian J. 6/2012)" @default.
- W2016586227 doi "https://doi.org/10.1002/asia.201290020" @default.
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