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- W2016589072 abstract "In paper I [N. C. Giebink, G. P. Wiederrecht, M. R. Wasielewski, and S. R. Forrest, Phys. Rev. B 82, 155305 (2010)], we proposed that current transport in a donor-acceptor heterojunction (HJ) depends on the balance of polaron pair (PP) dissociation and recombination. Here, we directly investigate these processes in archetype planar copper phthalocyanine $(text{CuPc})/{text{C}}_{60}$ and boron subpthalocyanine chloride $(text{SubPc})/{text{C}}_{60}$ HJs. Using intensity-modulated photocurrent spectroscopy (IMPS) along with emission from interfacial $text{Pc}/{text{C}}_{60}$ exciplex states, we monitor the geminate PP density at the HJ as a function of bias and illumination intensity. We find that the $text{SubPc}/{text{C}}_{60}$ PP density is limited by the dynamics of dissociation, where it increases from short circuit, and peaks at open circuit. In contrast, that of $text{CuPc}/{text{C}}_{60}$ is dominated by faster recombination kinetics and declines monotonically over the same voltage domain. We conclude that the PP recombination rate depends on electric field, and propose a simple expression that qualitatively explains the observed exciplex luminescence and IMPS behavior for these HJs. Our results provide insight into polaron pair recombination, which governs the current-voltage characteristics of organic heterojunctions in the dark and under illumination." @default.
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- W2016589072 date "2010-10-04" @default.
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- W2016589072 title "Ideal diode equation for organic heterojunctions. II. The role of polaron pair recombination" @default.
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- W2016589072 doi "https://doi.org/10.1103/physrevb.82.155306" @default.
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