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- W2016601518 abstract "Abstract The sulphidation behaviour of chromium alloys is reviewed in three different sulphur pressure ranges and the effect of chromium on the sulphidation kinetics and scale structures is discussed. It is generally known that chromium is resistant to sulphidation at high sulphur pressures, while it sulphidizes rapidly at low sulphur pressures. This seems to be due to phase changes from Cr2S3 or Cr3S4 to CrSx. At low sulphur pressures, copious internal sulphidation is formed for NiCr alloys whereas, for FeCr alloys, sulphidation is confined to grain boundaries. The sulphidation properties of chromium and Cr23C6 were investigated at 1073 K in the sulphur pressure range from 103.5 to 10−6 Pa. Both chromium and C23C6 showed similar kinetics and scale structures, except for the formation of Cr7C3 in the inner layer of sulphidized Cr23C6. It is concluded that, at the low sulphur pressures which often occur in an internal sulphidation zone, chromium and Cr23C6 sulphidize faster than the alloy substrate and also that the grain boundary sulphidation of FeCr alloys is due to the preferential sulphidation of chromium carbides and not of the chromium-depleted alloy matrix." @default.
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- W2016601518 date "1987-03-01" @default.
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- W2016601518 title "Sulphidation properties of chromium and chromium-containing alloys at high temperatures" @default.
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- W2016601518 doi "https://doi.org/10.1016/0025-5416(87)90360-0" @default.
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