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- W2016627988 endingPage "2021" @default.
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- W2016627988 abstract "Substitution reaction with ethylenediamine of coordinated glycinate ligand in bis(ethylenediamine)-glycinatocobalt(III) complex has been studied in the presence of photo-excited tris(2,2′-bipyridine)ruthenium(II) complex in alkaline aqueous solution (buffered around pH 12) containing 1.0M chloride ion at 25°C. VIS absorption and CD spectra were used for the racemate and the optically active isomers of the Co(III) complexes, respectively. The reaction was catalyzed by the excited Ru(II) complex to give tris(ethylenediamine)cobalt(III) complex. Mechanism of the ligand-substitution reaction and role of the excited Ru(II) complex were discussed." @default.
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- W2016627988 date "1985-11-13" @default.
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- W2016627988 title "Ligand Substitution Reaction of Bis(ethylenediamine)glycinatocobalt(III) Complex with Ethylenediamine Catalyzed by the Photo-excited Tris(2,2?-bipyridine)ruthenium(II) Complex" @default.
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- W2016627988 doi "https://doi.org/10.1002/hlca.19850680725" @default.
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