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• W2016641010 abstract "The reaction of [NO][PF6] with excess Ni powder in CH3NO2, in the presence of 2 mol % NiI2, results in the formation of [Ni(NO)(CH3NO2)3][PF6] (1), which can be isolated in modest yield as a blue crystalline solid. Also formed in the reaction is [Ni(CH3NO2)6][PF6]2 (2), which can be isolated in comparable yield as a pale-green solid. In the solid state, 1 exhibits tetrahedral geometry about the Ni center with a linear nitrosyl ligand [Ni1–N1–O1 = 174.1(8)°] and a short Ni–N bond distance [1.626(6) Å]. As anticipated, the weakly coordinating nitromethane ligands in 1 are easily displaced by a variety of donors, including Et2O, MeCN, and piperidine (NC5H11). More surprisingly, the addition of mesitylene to 1 results in the formation of an η6-coordinated nickel arene complex, [Ni(η6-1,3,5-Me3C6H3)(NO)][PF6] (6). In the solid state, complex 6 exhibits a long Ni–Ccent distance [1.682(2) Å], suggesting a relatively weak Ni–arene interaction, a consequence of the strong π-back-donation to the nitrosyl ligand. The addition of anisole to 1 also results in the formation of a η6 nickel arene complex, [Ni(η6-MeOC6H5)(NO)][PF6] (7). This complex also exhibits a long Ni–Ccent distance [1.684(1) Å]." @default.
• W2016641010 created "2016-06-24" @default.
• W2016641010 creator A5053893566 @default.
• W2016641010 creator A5057270850 @default.
• W2016641010 creator A5086274379 @default.
• W2016641010 date "2011-10-27" @default.
• W2016641010 modified "2023-09-29" @default.
• W2016641010 title "Late-Metal Nitrosyl Cations: Synthesis and Reactivity of [Ni(NO)(MeNO₂)₃][PF₆]" @default.
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• W2016641010 doi "https://doi.org/10.1021/ic201821t" @default.
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