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- W2016641230 abstract "The interaction of HNCO with Pt(110) surface has been investigated by different techniques at low and high-temperatures. The adsorption of HNCO on Pt(110) caused no reordering of the surface Pt atoms from the (1 × 2) to the (1 × 1) structure. At saturation, an ordered (2 × 2) structure was formed, HNCO was detected in the desorbing gases only after its low temperature (110 K) adsorption; it desorbed in two stages, with peak maxima at 150 and 270 K. In addition, the formation of H2 (Tmax ~ 290 K) and NH3 (Tmax ~ 293 and 390 K) was also observed. When the temperature was raised to above 400 K, N2 and CO evolution was noticed, but neither NCO nor (NCO)2 species were found in the desorbing gases. The adsorption of HNCO at 110 K produced a very intense loss at 10.4 eV and a less intense one at 13.5 eV in the electron energy loss spectra. From the behaviour of these losses at higher temperature it was inferred that the dissociation of adsorbed NCO species to adsorbed N and CO begins to an appreciable extent above 230 K, and that the dissociation is complete at 310–330 K. It is proposed that NCO is located in the “trough sites” of the corrugated surface of (1 × 2) structure and that it is multiply bonded to the Pt atoms." @default.
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- W2016641230 title "Adsorption and surface dissociation of HNCO on Pt(110) surfaces: LEED, AES, ELS and TDS studies" @default.
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- W2016641230 doi "https://doi.org/10.1016/0039-6028(81)90570-7" @default.
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