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- W2016641286 abstract "Abstract The Zeeman spectrum of the NO molecule in the X 2 Π 1 2 , J = 1 2 and J = 3 2 rotational states has been studied using a molecular beam electric resonance spectrometer. High-resolution data were obtained in magnetic fields ranging from 0.1 to 0.8 T. The present measurements are combined with relevant data from the literature in a least-squares fit to determine basic molecular g factors. Seven molecular g factors and the anisotropy in the magnetic susceptibility could be determined, and a value of the electronic quadrupole moment Q|e was derived. The most prominent results are gs = 2.002095(40) and Q|e = −1.201(11) × 10−38 C m2, to be compared with the respective ab initio values which are 2.002087 and −0.826 × 10−38 C m2. Furthermore, separate contributions from 2Σ+, 2Σ−, and Δ2 states to the electronic part of the rotational g factor were obtained, showing that the unique perturber approximation is invalid for the present example. Finally, the combination of Zeeman- and zero-field data enabled a separate determination of the spin-rotation constant and the centrifugal distortion in the spin-orbit coupling (AD). The value of AD derived from experiment is −1.43(20) MHz, in good agreement with the theoretical prediction of −1.92(8) MHz." @default.
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- W2016641286 title "The Zeeman spectrum of the NO molecule" @default.
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- W2016641286 doi "https://doi.org/10.1016/0022-2852(80)90110-1" @default.
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