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• W2016641372 abstract "We developed a liquid crystal (LC) sensor system for detecting mercuric ion (Hg(2+)) in aqueous solutions. In this system, 4-cyano-4'-pentyl biphenyl (5CB) was doped with a sulfur- and nitrogen-containing ligand 5-(pyridine-4-yl)-2-(5-(pyridin-4-yl)thiophen-2-yl)thiazole (ZT) as the Hg(2+) specific LCs. When the system was immersed in the solution containing Hg(2+), the complex of ZT and Hg(2+) formed, which disrupted the orientation of LC and lead to a dark-to-bright transition of the image of LCs. From mercuric binding titrations monitored by UV-vis spectroscopy, it was found that 1:1 Hg(2+)/ZT complexes were formed. The limit of detection (LOD) of the system to Hg(2+) is 10 μM, and it did not respond to Cd(2+), Zn(2+), Cu(2+), Pb(2+), Fe(+), Mg(2+), Ca(2+), Na(+), and K(+). Besides, we also demonstrated that this system is capable of detecting Hg(2+) in tap water and pond water. Because the signal of this system is colorful under ambient light, which is readily understood by normal users, it can be used as a portable device to monitor the water quality at any location." @default.
• W2016641372 created "2016-06-24" @default.
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• W2016641372 date "2015-04-07" @default.
• W2016641372 modified "2023-10-14" @default.
• W2016641372 title "Ligand-Doped Liquid Crystal Sensor System for Detecting Mercuric Ion in Aqueous Solutions" @default.
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• W2016641372 doi "https://doi.org/10.1021/acs.analchem.5b00675" @default.
• W2016641372 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25824970" @default.
• W2016641372 hasPublicationYear "2015" @default.
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