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- W2016644201 abstract "Abstract Theoretical expressions for the molecular parameters in the effective rotorsional Hamiltonian in a strong magnetic field are derived from a second order perturbation treatment within the electronic states which was adapted to the presence of a large am plitude internal motion. The technique developed m ay be o f use also in other applications where it should be necessary to go beyond the Born-Oppenheimer approximation. By use o f the theoretical expressions it is now possible to use experimentally determined Zeeman data to derive “experimental values” for the molecular electric quadrupole moments, the paramagnetic susceptibilities, the second m om ents o f the electron charge distribution, and the sign of the molecular electric dipole moment also for low barrier molecules." @default.
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- W2016644201 date "1978-12-01" @default.
- W2016644201 modified "2023-09-25" @default.
- W2016644201 title "The Rotational Zeeman Effect of Molecules with Low Barrier Internal Rotation. II. Derivation of the Effective Rotorsional Hamiltonian" @default.
- W2016644201 doi "https://doi.org/10.1515/zna-1978-1217" @default.
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