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- W2016644345 abstract "Pelargonidin-3-glucoside has been isolated from the acidified methanolic extract of strawberries (Fragaria anannassa variety Corona) by successive application of an ion-exchange resin, droplet-counter chromatography and gel filtration. The pigment in acidified methanolic solution was studied by means of the two-dimensional nuclear Overhauser enhancement NMR technique, and the sugar unit was found to be attached to the 3-position on the aglycone. At +20 degrees C the pigment was found to be in the extreme narrowing limit where the NOESY cross-peaks are negative. However, at -20 degrees C this low-mass anthocyanin could be studied in the slow motion regime where the NOESY cross-peaks are positive. With a mixing time of 0.3 s, the glucose H1-H4 proton pair was measured in the initial cross-relaxation rate and their cross-peak volume corresponded to the H1-H4 distance found in a 4C1 chair conformation." @default.
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- W2016644345 date "1992-01-01" @default.
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- W2016644345 title "Two-dimensional Nuclear Overhauser Enhancement NMR Experiments on Pelargonidin-3-glucopyranoside, an Anthocyanin of Low Molecular Mass." @default.
- W2016644345 doi "https://doi.org/10.3891/acta.chem.scand.46-0872" @default.
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