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- W2016644818 abstract "Abstract The hydrothermal reaction of lead( II ) carbonate with 3‐sulfobenzoic acid, 3‐HO 3 S−C 6 H 4 −CO 2 H, and isopropylimino‐bis(methylenephosphonic acid), (CH 3 ) 2 CHN(CH 2 PO 3 H 2 ) 2 (H 4 L 1 ), gave a new layered lead( II ) carboxylate‐phosphonate, Pb 7 (3‐O 3 S−C 6 H 4 −CO 2 )(L 1 ) 3 (H 2 O) 2 ·2H 2 O ( 1 ), whereas the hydrothermal reaction of lead( II ) carbonate with 1 , 3,5‐benzenetricarboxylic acid (H 3 BTC) and N ‐cyclohexylimino‐bis(methylenephosphonic acid), C 6 H 11 N(CH 2 PO 3 H 2 ) 2 (H 4 L 2 ), afforded a layered complex, Pb 3 (HL 2 )(H 2 L 2 )(H 2 BTC)(H 2 O)·H 3 BTC·H 2 O ( 2 ). The structure of complex 1 contains <010> lead( II ) carboxylate‐phosphonate hybrid layers, with the sulfonate group of the carboxylate‐sulfonate ligand as the pendant group. In complex 2 , the lead( II ) ions are interconnected through bridging diphosphonate ligands, and results in the formation of a lead( II ) diphosphonate slab, which are further interlinked via hydrogen bonds between non‐coordinated phosphonate oxygen atoms to form a <001> layer. The doubly protonated H 2 BTC anion is bidentately chelated to a lead( II ) ion through a carboxylate group, whereas the neutral H 3 BTC ligand is intercalated between two layers, forming hydrogen bonds with the non‐coordinated carboxylate groups of the H 2 BTC anion. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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- W2016644818 title "Novel Layered Lead(<scp>II</scp>) Aminodiphosphonates with Carboxylate‐Sulfonate and 1,3,5‐Benzenetricarboxylate Ligands as Pendant Groups or Intercalated Species" @default.
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- W2016644818 doi "https://doi.org/10.1002/ejic.200300607" @default.
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