Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016646207> ?p ?o ?g. }
- W2016646207 endingPage "67" @default.
- W2016646207 startingPage "59" @default.
- W2016646207 abstract "Zeolite catalyzed deoxygenation of small oxygenates present in bio-oil or selected as model compounds was performed under Methanol-to-Hydrocarbons (MTH) like reaction conditions using H-ZSM-5 as the catalyst. Co-feeding of the oxygenates with methanol generally decreases catalyst lifetime due to coking and results in higher selectivity towards aromatics compared to conversion of pure methanol. The reaction pattern of the different oxygenates did not simply follow the effective H/C ratio of the additives since structural isomers with identical effective H/C ratios showed significant differences with respect to catalyst lifetime and product selectivity. A distinct positive effect on catalyst lifetime was observed for methanol dilution. Thus, the conversion capacity of the catalyst was up to 10 times higher when the reactant was diluted in methanol. We observe that in particular acid/ester functionalities favor oxygen removal through decarbonylation over dehydration which preserves hydrogen in the hydrocarbon product mixture. By employing 13C labeled substrates we confirmed the incorporation of carbon into the hydrocarbon products as well as a pronounced preference of the additive carbon towards incorporation into aromatic compounds." @default.
- W2016646207 created "2016-06-24" @default.
- W2016646207 creator A5020656110 @default.
- W2016646207 creator A5045620900 @default.
- W2016646207 date "2011-04-01" @default.
- W2016646207 modified "2023-10-17" @default.
- W2016646207 title "Utilization of biomass: Conversion of model compounds to hydrocarbons over zeolite H-ZSM-5" @default.
- W2016646207 cites W171016720 @default.
- W2016646207 cites W1963783730 @default.
- W2016646207 cites W1971561270 @default.
- W2016646207 cites W1972903468 @default.
- W2016646207 cites W1974508831 @default.
- W2016646207 cites W1980245408 @default.
- W2016646207 cites W1982773285 @default.
- W2016646207 cites W1986132760 @default.
- W2016646207 cites W1986703948 @default.
- W2016646207 cites W1988148113 @default.
- W2016646207 cites W1992251483 @default.
- W2016646207 cites W1999287320 @default.
- W2016646207 cites W2004919955 @default.
- W2016646207 cites W2005634799 @default.
- W2016646207 cites W2009224215 @default.
- W2016646207 cites W2010685428 @default.
- W2016646207 cites W2017447613 @default.
- W2016646207 cites W2021544033 @default.
- W2016646207 cites W2027641427 @default.
- W2016646207 cites W2030420496 @default.
- W2016646207 cites W2031822566 @default.
- W2016646207 cites W2035280974 @default.
- W2016646207 cites W2036228650 @default.
- W2016646207 cites W2050134316 @default.
- W2016646207 cites W2051700384 @default.
- W2016646207 cites W2052280594 @default.
- W2016646207 cites W2053773639 @default.
- W2016646207 cites W2057451527 @default.
- W2016646207 cites W2059836177 @default.
- W2016646207 cites W2063133980 @default.
- W2016646207 cites W2066524922 @default.
- W2016646207 cites W2077059389 @default.
- W2016646207 cites W2078450813 @default.
- W2016646207 cites W2079595387 @default.
- W2016646207 cites W2080277329 @default.
- W2016646207 cites W2087385869 @default.
- W2016646207 cites W2094805740 @default.
- W2016646207 cites W2094991496 @default.
- W2016646207 cites W2101522378 @default.
- W2016646207 cites W2104119823 @default.
- W2016646207 cites W2113584671 @default.
- W2016646207 cites W2120446525 @default.
- W2016646207 cites W2127350857 @default.
- W2016646207 cites W2143711546 @default.
- W2016646207 cites W2146443004 @default.
- W2016646207 cites W2150430067 @default.
- W2016646207 cites W2156421428 @default.
- W2016646207 cites W2159317682 @default.
- W2016646207 cites W4210975641 @default.
- W2016646207 doi "https://doi.org/10.1016/j.apcata.2011.01.040" @default.
- W2016646207 hasPublicationYear "2011" @default.
- W2016646207 type Work @default.
- W2016646207 sameAs 2016646207 @default.
- W2016646207 citedByCount "66" @default.
- W2016646207 countsByYear W20166462072012 @default.
- W2016646207 countsByYear W20166462072013 @default.
- W2016646207 countsByYear W20166462072014 @default.
- W2016646207 countsByYear W20166462072015 @default.
- W2016646207 countsByYear W20166462072016 @default.
- W2016646207 countsByYear W20166462072017 @default.
- W2016646207 countsByYear W20166462072018 @default.
- W2016646207 countsByYear W20166462072019 @default.
- W2016646207 countsByYear W20166462072020 @default.
- W2016646207 countsByYear W20166462072021 @default.
- W2016646207 countsByYear W20166462072022 @default.
- W2016646207 countsByYear W20166462072023 @default.
- W2016646207 crossrefType "journal-article" @default.
- W2016646207 hasAuthorship W2016646207A5020656110 @default.
- W2016646207 hasAuthorship W2016646207A5045620900 @default.
- W2016646207 hasBestOaLocation W20166462072 @default.
- W2016646207 hasConcept C108285982 @default.
- W2016646207 hasConcept C118792377 @default.
- W2016646207 hasConcept C132190689 @default.
- W2016646207 hasConcept C161790260 @default.
- W2016646207 hasConcept C178790620 @default.
- W2016646207 hasConcept C185592680 @default.
- W2016646207 hasConcept C2777207669 @default.
- W2016646207 hasConcept C2778077586 @default.
- W2016646207 hasConcept C2778533180 @default.
- W2016646207 hasConcept C2779607525 @default.
- W2016646207 hasConcept C2779778602 @default.
- W2016646207 hasConceptScore W2016646207C108285982 @default.
- W2016646207 hasConceptScore W2016646207C118792377 @default.
- W2016646207 hasConceptScore W2016646207C132190689 @default.
- W2016646207 hasConceptScore W2016646207C161790260 @default.
- W2016646207 hasConceptScore W2016646207C178790620 @default.
- W2016646207 hasConceptScore W2016646207C185592680 @default.
- W2016646207 hasConceptScore W2016646207C2777207669 @default.
- W2016646207 hasConceptScore W2016646207C2778077586 @default.
- W2016646207 hasConceptScore W2016646207C2778533180 @default.
- W2016646207 hasConceptScore W2016646207C2779607525 @default.