Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016655478> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2016655478 endingPage "92" @default.
- W2016655478 startingPage "89" @default.
- W2016655478 abstract "The constrained structure of bicyclic aminophosphites L 3,3,7,7-tetramethyl-2,8-dioxa-5-aza-1-phosphabicyclo(3,3,0)octane (La) and 3,7-dimethyl-2-8-dioxa-5-aza-1-phosphabicyclo(3,3,0)octane (Lb) leads to the restoration of the donor properties of the nitrogen adjacent to the phosphorus atom. This is illustrated by the facile formation of 1:1 adducts with tungsten(VI) alkoxide WO(Ome)4, the metal attaining hexacoordination by attachment of the ligand through the nitrogen. Oxido-reduction reactions in the coordination sphere between the W(IV) and P(III) centers, which provide bicyclic alkoxyphosphorane, prevented the isolation of these WO(OMe)4·L adducts. Stabilization was achieved by additional coordination of the phosphorous lone pair by a BH3 moiety. A mixed adduct WO(OMe)4· La·BH3, which represents the first tungsten oxoalkoxide adduct reported so far was isolated. The bicyclic aminophosphites L behave as P-donors towards less hard Lewis acids, even W(VI) derivatives. Thus WOCl4(La)2, cis-PtCl2(La)2 and [Rh(μCl)(C2H4)La]2 were isolated and characterized. The large metal phosphorus coupling constants compare favorably with those of common phosphites." @default.
- W2016655478 created "2016-06-24" @default.
- W2016655478 creator A5050394283 @default.
- W2016655478 date "1984-09-01" @default.
- W2016655478 modified "2023-10-18" @default.
- W2016655478 title "Bicylic aminophosphites as N-Donors towards W(VI) oxoalkoxides" @default.
- W2016655478 cites W1963898401 @default.
- W2016655478 cites W1971719743 @default.
- W2016655478 cites W1973166932 @default.
- W2016655478 cites W2008407186 @default.
- W2016655478 cites W2035734686 @default.
- W2016655478 cites W2085121368 @default.
- W2016655478 cites W2949310894 @default.
- W2016655478 cites W2949877591 @default.
- W2016655478 cites W2951025458 @default.
- W2016655478 cites W2951971563 @default.
- W2016655478 cites W3005478113 @default.
- W2016655478 cites W3138683333 @default.
- W2016655478 doi "https://doi.org/10.1016/s0020-1693(00)81877-0" @default.
- W2016655478 hasPublicationYear "1984" @default.
- W2016655478 type Work @default.
- W2016655478 sameAs 2016655478 @default.
- W2016655478 citedByCount "5" @default.
- W2016655478 crossrefType "journal-article" @default.
- W2016655478 hasAuthorship W2016655478A5050394283 @default.
- W2016655478 hasConcept C108204754 @default.
- W2016655478 hasConcept C11111787 @default.
- W2016655478 hasConcept C116569031 @default.
- W2016655478 hasConcept C155647269 @default.
- W2016655478 hasConcept C161790260 @default.
- W2016655478 hasConcept C163638829 @default.
- W2016655478 hasConcept C170493617 @default.
- W2016655478 hasConcept C178790620 @default.
- W2016655478 hasConcept C185592680 @default.
- W2016655478 hasConcept C24961977 @default.
- W2016655478 hasConcept C2775995839 @default.
- W2016655478 hasConcept C2776568683 @default.
- W2016655478 hasConcept C2776624427 @default.
- W2016655478 hasConcept C2778839380 @default.
- W2016655478 hasConcept C32909587 @default.
- W2016655478 hasConcept C46000676 @default.
- W2016655478 hasConcept C544153396 @default.
- W2016655478 hasConcept C55493867 @default.
- W2016655478 hasConcept C71240020 @default.
- W2016655478 hasConceptScore W2016655478C108204754 @default.
- W2016655478 hasConceptScore W2016655478C11111787 @default.
- W2016655478 hasConceptScore W2016655478C116569031 @default.
- W2016655478 hasConceptScore W2016655478C155647269 @default.
- W2016655478 hasConceptScore W2016655478C161790260 @default.
- W2016655478 hasConceptScore W2016655478C163638829 @default.
- W2016655478 hasConceptScore W2016655478C170493617 @default.
- W2016655478 hasConceptScore W2016655478C178790620 @default.
- W2016655478 hasConceptScore W2016655478C185592680 @default.
- W2016655478 hasConceptScore W2016655478C24961977 @default.
- W2016655478 hasConceptScore W2016655478C2775995839 @default.
- W2016655478 hasConceptScore W2016655478C2776568683 @default.
- W2016655478 hasConceptScore W2016655478C2776624427 @default.
- W2016655478 hasConceptScore W2016655478C2778839380 @default.
- W2016655478 hasConceptScore W2016655478C32909587 @default.
- W2016655478 hasConceptScore W2016655478C46000676 @default.
- W2016655478 hasConceptScore W2016655478C544153396 @default.
- W2016655478 hasConceptScore W2016655478C55493867 @default.
- W2016655478 hasConceptScore W2016655478C71240020 @default.
- W2016655478 hasIssue "1" @default.
- W2016655478 hasLocation W20166554781 @default.
- W2016655478 hasOpenAccess W2016655478 @default.
- W2016655478 hasPrimaryLocation W20166554781 @default.
- W2016655478 hasRelatedWork W1982292429 @default.
- W2016655478 hasRelatedWork W2016655478 @default.
- W2016655478 hasRelatedWork W2085016392 @default.
- W2016655478 hasRelatedWork W2105808967 @default.
- W2016655478 hasRelatedWork W2155372884 @default.
- W2016655478 hasRelatedWork W2245214212 @default.
- W2016655478 hasRelatedWork W2474337329 @default.
- W2016655478 hasRelatedWork W2950228926 @default.
- W2016655478 hasRelatedWork W2951207350 @default.
- W2016655478 hasRelatedWork W4256417135 @default.
- W2016655478 hasVolume "88" @default.
- W2016655478 isParatext "false" @default.
- W2016655478 isRetracted "false" @default.
- W2016655478 magId "2016655478" @default.
- W2016655478 workType "article" @default.