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• W2016661251 abstract "Peptide coupling of benzene-1,3,5-carboxylic acid with 3 equiv of histidine ethyl ester or cysteine ethyl ester has yielded the tripodal pseudopeptide ligands THB and H(3)TCB. Likewise, the combination of tris(carboxyethyl)nitromethane with 3 equiv of cysteine ethyl ester gave the tripod H(3)TCM. With zinc salts, the pseudopeptides form the insoluble compounds (THB)(2)Zn(5)Cl(10), Zn(3)(TCB)(2), and Zn(3)(TCM)(2) which are likely to be coordination polymers. Solution studies of THB with potentiometric methods have identified the complex species [(THB)(2)Zn](2+), [(THB)Zn-OH(2)](2+), and [(THB)Zn-OH](+). The pK(a) of the zinc-bound water molecule is 6.2, making the (THB)Zn complex a viable model of carbonic anhydrase." @default.
• W2016661251 created "2016-06-24" @default.
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• W2016661251 date "2002-04-05" @default.
• W2016661251 modified "2023-09-24" @default.
• W2016661251 title "Tripodal Pseudopeptides with Three Histidine or Cysteine Donors: Synthesis and Zinc Complexation" @default.
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• W2016661251 doi "https://doi.org/10.1021/ic011263c" @default.
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