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- W2016661917 abstract "The free-radical polymerization of vinyl acetate (VAc) was carried out in various alcoholic solvents. Fluoroalcohols with a lower pKa and higher bulkiness were effective in enhancing the syndiotactic specificity of the polymerization. The polymerization of VAc in perfluoro-tert-butyl alcohol ((CF3)3COH) at -78°C led to a dyad syndiotacticity of 72%, which is the highest value reported for the radical polymerization of vinyl esters. Hydrogen-bonding between the acetyl groups of VAc and polymer and the fluoroalcohol molecule may be responsible for the enhancement of the syndiotactic specific propagation." @default.
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- W2016661917 date "1998-01-01" @default.
- W2016661917 modified "2023-10-11" @default.
- W2016661917 title "Stereospecific polymerization of vinyl acetate in fluoroalcohols. Synthesis of syndiotactic poly(vinyl alcohol)." @default.
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- W2016661917 doi "https://doi.org/10.2183/pjab.74.46" @default.
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