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- W2016682590 abstract "Fractions of poly(trimethylene oxide) CH2)3]x of relatively high degree of polymerization x were studied in liquid-liquid phase equilibria in the poor solvent cyclohexane. The results thus obtained indicate that the ideal or theta-temperature for this system is 27.0 ± 0.5°C. Intrinsic viscosities measured under these conditions were used to obtain a value for the characteristic ratio 〈r2〉0nl2 of the unperturbed dimensions of these chains relative to the number of skeletal bonds and the average square of their length. The resulting value, 3.86 ± 0.08, is unusually low, a fact which may be attributed to the high degree of conformational randomness in this chain molecule. Consideration of poly(trimethylene oxide) to be an alternating copolymer of ethylene and oxymethylene provides some additional information of interest. It clearly demonstrates that a chemical copolymer can have configuration-dependent properties which are vastly different from those of its parent homopolymers." @default.
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- W2016682590 title "Dimensions of poly(trimethylene oxide) chains in a theta-solvent" @default.
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- W2016682590 doi "https://doi.org/10.1016/0032-3861(76)90205-6" @default.
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