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• W2016702444 abstract "A model has been presented to correlate both the density and molar volume of Bi 2 O 3 –B 2 O 3 glasses with the structure. The model makes use of the available data of the fraction of four coordinated boron to get the concentration of all structural units. The concentration of BO 4 units shows a maximum at ~ 31 mol% Bi 2 O 3 . There is a nonlinear decrease in the concentration of symmetric BO 3 units and an increase in the concentration of BiO 6 units. Asymmetric BO 3 units start forming for Bi 2 O 3 > 42 mol%. It is deduced that in BiO 6 units, oxygen atoms are four coordinated with Bi atoms. The model is able to fit the calculated and experimental density and molar volume and explains the minimum in the molar volume at 22 mol% Bi 2 O 3 . • The article presents density–structure correlations of Bi 2 O 3 –B 2 O 3 glasses. • Values of N 4 could be used to calculate the concentration of structural species. • Oxygen atoms in BiO 6 units must be four coordinated with Bi atoms. • Data and trends of calculated D and V m agree well with the experimental ones. • A minimum in V m at 22 mol% Bi 2 O 3 could be explained in terms of structure." @default.
• W2016702444 created "2016-06-24" @default.
• W2016702444 creator A5063294675 @default.
• W2016702444 date "2014-11-01" @default.
• W2016702444 modified "2023-09-24" @default.
• W2016702444 title "Insights into the structure of Bi2O3–B2O3 glasses as predicted from density correlations" @default.
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• W2016702444 doi "https://doi.org/10.1016/j.jnoncrysol.2014.07.045" @default.
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