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• W2016704471 abstract "Broadband dielectric spectroscopy was employed to investigate the kinetics of the mutarotation of d-fructose. In this article, d-fructose tautomerization behavior in pure melt is revealed. By monitoring structural relaxation time shift, we were able to determine speed in temperature range 303−333 K and the activation energy for this phenomenon. It is equal to 107 kJ/mol, which is very high in comparison to the solvated system. We have also shown the influence of this process to the γ-relaxation (secondary relaxation process). Dielectric spectroscopy derived complex information about mutarotational dynamics." @default.
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• W2016704471 date "2009-03-02" @default.
• W2016704471 modified "2023-10-16" @default.
• W2016704471 title "Mutarotation in <scp>d</scp>-Fructose Melt Monitored by Dielectric Spectroscopy" @default.
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• W2016704471 doi "https://doi.org/10.1021/jp8095902" @default.
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