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• W2016710085 endingPage "961" @default.
• W2016710085 startingPage "949" @default.
• W2016710085 abstract "Diorganomonothiophosphinato-triphenylmetal(IV) derivatives, Ph3M(OSPR@) (M = Ge, Sn, Pb; R = Me, Et, Ph), were prepared and investigated. The IR and multinuclear (1H, 13C, 31P) NMR spectra are discussed in relation to the MO and/or MS bonding of the ambident OSPR2− ligand. The crystal and molecular structures of Ph3Ge[O(S)PPh2] (1) and [Ph2Sn{O(S)PPh2} (μ-OH)]2 (2) were determined by X-ray diffractometry. The asymmetric unit for Ph3Ge[O(S)PPh2] contains two independent molecules. The monothiophosphinato group is bonded to germanium only through oxygen (av. GeO 1.826, Ge···S 3.892 Å), leading to a tetrahedral coordination around the germanium atom. The crystal of [Ph2Sn{O(S)PPh2} (μ-OH)]2 consists of dimeric units built up through SnOSn bridges involving the oxygen atom of the hydroxy groups. The monothiophosphinato group is again monodentate [Sn(1)O(1) 2.089(3), Sn(1)···S(1) (non-bonding) 4.164 Å] and the coordination geometry around tin is trigonal bipyramidal, with the O(1) atom of the phosphorus ligand and the O(2′) atome of a bridging hydroxy group in axial positions." @default.
• W2016710085 created "2016-06-24" @default.
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• W2016710085 date "1997-01-01" @default.
• W2016710085 modified "2023-09-24" @default.
• W2016710085 title "Metal-oxygen versus metal-sulfur bonding of the ambident monothiophosphinato ligand in some triphenylmeta(IV) derivatives, Ph3M[OSPR2] (M = Ge, Sn, Pb). Crystal structures of Ph3Ge[O(S)PPh2] and [Ph2Sn{O(S)PPh2} (μ-OH)]2" @default.
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• W2016710085 doi "https://doi.org/10.1016/s0277-5387(96)00354-3" @default.
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