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- W2016747900 abstract "In order to establish the atomic order (or disorder) of Li atoms in LiFe5O8, a crystallographic structure refinement and a spectroscopic Mössbauer study are made. Several polycrystalline and monocrystalline samples are separately heat treated and studied. The results are in agreement with the existence of a short-range order in the disordered phase. An exact fit of the Mössbauer spectra is done and distinguishes three FeB sites and two FeA sites magnetically inequivalent. The calulated dipolar fields are consistent with values determined by NMR. Un affinement de la structure cristallographique et une étude par spectroscopie Mössbauer ont été réalisés dans LiFe5O8, en vue de préciser l'ordre (ou le désordre) des atomes de lithium. Plusieurs échantillons polycristallins et monocristallins ayant subi des traitements thermiques différents ont été étudiés. Les résultats sont en accord avec l'existence d'un ordre à courte distance dans la phase désordonnée. La décomposition exacte des spectres Mössbauer a été établie et a permis de distinguer pour le fer trois sites B et deux sites A magnétiquement inéquivalents; les champs dipolaires obtenus sont cohérents avec ceux détermines par RMN." @default.
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- W2016747900 date "1983-06-16" @default.
- W2016747900 modified "2023-10-17" @default.
- W2016747900 title "Cation Ordering in LiFe5O8 Studied by Mössbauer Spectroscopy and X-Ray Crystallography" @default.
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- W2016747900 doi "https://doi.org/10.1002/pssa.2210770225" @default.
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