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- W2016752757 abstract "[graph: see text] High-level ab initio calculations indicate that *CH3 addition to the sulfur center of S=P(Z)(Z')SCH3 (Z,Z' = CH3, CN, OCH3, Ph) is considerably less exothermic than addition to the corresponding RAFT agents, S=C(Z)SCH3. This suggests that dithiophosphinate esters may have only limited use in controlling free-radical polymerization, but should make excellent radical chain carriers in organic synthesis. The results cast doubt on the notion that phosphoranyl radicals are more intrinsically stabilized than carbon-centered radicals." @default.
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- W2016752757 date "2005-09-17" @default.
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- W2016752757 title "Should Dithiophosphinate Esters Function as RAFT Agents?" @default.
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- W2016752757 doi "https://doi.org/10.1021/ol0516420" @default.
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